Testing Adsorbents Capacities For
Indoor Volatile Organic Compounds At
Optimum Operating Conditions
Author(s)
W. S. Bouhamra, A. S. Elkilani & C. G. J. Baker
Abstract
Measurements of adsorption isotherms for three VOCs (toluene, 1,2
dichlorobenzene and 1,1,1 trichloroethane) on five adsorbents (polyacrylonitrile
carpet fibers, silica alumina, silica alumina impregnated with KMnO4, granulated
activated carbon and pellets of activated carbon) were performed. Various
temperatures and relative humidity were tested. VOCs concentrations were
altered in the range of presence in indoor environments in Kuwait. The adsorbed
weight was measured in a thermogravimetric analyser. Linear isotherms were
observed in all cases with values of the Henry coefficient ranging from 0.01 to
0.941 mm. Silica alumina activated by KMnO4 showed highest adsorption rates.
At low temperatures and minimum humidity in air high equilibrium constants
were observed, since adsorption rate is higher than desorption rates at lower
temperatures. In addition, increasing humidity will decrease adsorption rates due
to moisture occupation of the available voids for adsorption, especially for
hydrophilic adsorbents. There was good agreement between the equilibrium and
kinetic constants obtained in the TGA. It may therefore be concluded that, in the
present case at least, adsorption data obtained using small samples of adsorbent
in the laboratory can be successfully scaled-up and used in combination with the
theory described in this work to model indoor air quality in much larger
chambers.
1 Introduction
Volatile Organic Compounds (VOCs) may present an IAQ problem, when
individual organic compounds or their mixtures exceed certain concentrations.
Most of VOCs are classified as carcinogens. In theory, the removal of gaseous
Keywords
Related Book
Other papers in this volume
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