Transport Phenomena In An Electrochemical
Rotating Cylinder Reactor
Author(s)
F. Tomasoni, J. F. Thomas, D. Yildiz, J. van Beeck
& J. Deconinck
Abstract
Electrochemical processes are at the heart of a wide variety of both basic and
advanced industrial activities. In many industrial electrochemical applications
high flow rates are applied such that the electrochemical process is convectivetransport-
dependent. In order to obtain the mass and charge transfer from the
solution to the surface of the electrodes the flow field characterization is therefore
essential.
In view of understanding in detail such processes, this paper presents the
preliminary characterization of the complex flow field that takes place in an
electrochemical rotating cylinder reactor (short aspect ratio Γ = 1.7 and wide
gap η = 0.16). For this purpose a combined experimental, numerical and
theoretical approach is followed. The experimental characterization is performed
using time-resolved Particle Image Velocimetry (PIV), a non-intrusive and laserbased
experimental technique. Special attention is paid to the image processing
and possible optical problems. The investigation is performed for different flow
conditions, from moderate (1700) to high (13600) Reynolds number.
The experimental results have been compared to the velocity profiles obtained
using RANS and DNS simulations.
The theoretical part of this study is to provide new analytical models based
on the solution of the momentum boundary layer equation and of the mass and
charge transport equations. The analytical velocity profile agrees well with the
experimental data.
Keywords: rotating cylinder electrode, PIV, RANS, DNS.
Keywords
rotating cylinder electrode, PIV, RANS, DNS.
Related Book
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