Ultrasound Assisted Removal Of
Estrogen Hormones
Author(s)
R. P. Suri, G. Andaluri, S. Abburi & M. Velicu
Abstract
Estrogen compounds are being detected in significant concentrations in surface
water, wastewater, soil, sediments and groundwater. These estrogenic
compounds influence the growth and performance of the reproductive system.
Several reports indicate that the major source of these contaminants to the
ecosystem is the effluents from wastewater treatment plants. These contaminants
are found at significant concentrations in the effluent and the water bodies into
which they are discharged. Reports also indicate that these estrogens are found in
trace level concentrations in drinking water. Conventional treatment technologies
are not designed to completely remove these pharmaceutically active chemicals
(PhACs). Therefore there is a need to develop new treatment technologies in
addition to the existing technologies. Ultrasound is an advanced oxidation
process that effectively destroys many toxic organic chemicals. Ultrasound
involves the process of passing high frequency sound waves into the liquid
media. These sound waves create acoustic cavitations in the liquid media. The
removal of these chemicals occurs through three different mechanisms, which
are thermal degradation in the cavitation region, supercritical oxidation and
hydroxyl radical oxidation in the interfacial or the bulk region. In the current
work, ultrasound technology is employed as a mechanism of removal of several
estrogen hormones. The estrogens targeted in this study were 17α-estradiol, 17β-
estradiol, estrone, estriol, 17α-dihydroequilin, 17α-ethinyl-estradiol and equilin.
Also included in the results are the effect of various process conditions such as
variation of pH and presence of oxidizing agents on the removal of estrogens.
The degradation rates for each of the estrogen compound have been investigated
in clean water. The effect of ionic strength of the system and the system
alkalinity are also presented.
Keywords: estrogen hormones, ultrasound, pH, alkalinity, salt, peroxide.
Keywords
estrogen hormones, ultrasound, pH, alkalinity, salt, peroxide.
Related Book
Other papers in this volume
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